ikbguИзвестия Кабардино-Балкарского государственного университетаProceedings of the Kabardino-Balkarian State University2221-7789Kabardino-Balkarian State University named after Kh. M. Berbekov10.31143/2221-7789-2024-4-45-51XPXHDYikbgu-142Research ArticleХимияChemistryПОЛИМЕРИЗАЦИЯ ВИНИЛЬНЫХ МОНОМЕРОВ С УЧАСТИЕМ ЧЕТВЕРТИЧНОГО АММОНИЕВОГО КОМПЛЕКСАPOLYMERIZATION OF VINYL MONOMERS WITH THE PARTICIPATION OF A QUATERNARY AMMONIUM COMPLEXМалкандуевЮ. А.MalkanduevYu. A.malkanduev@mail.ruДжалиловА. Т.DzhalilovA. T.malkanduev@mail.ruКяровА. А.KyarovA. A.malkanduev@mail.ruГриневаЛ. Г.GrinevaL. G.malkanduev@mail.ruКабардино-Балкарский государственный университет им. Х.М. БербековаKabardino-Balkarian State UniversityТашкентский научно-исследовательский химико-технологический институтTashkent Scientific Research Institute of Chemical Technology2024301220241444551Copyright © Малкандуев Ю.А., Джалилов А.Т., Кяров А.А., Гринева Л.Г., 20242024Малкандуев Ю.А., Джалилов А.Т., Кяров А.А., Гринева Л.Г.Malkanduev Y.A., Dzhalilov A.T., Kyarov A.A., Grineva L.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.izvestiakbsu.ru/jour/article/view/142

В работе рассматриваются процессы полимеризации винильных мономеров в присутствии инициирующих систем амин – алкилирующий агент, с образованием четвертичных аммониевых соединений. При изучении механизмов полимеризации обнаружена схожесть полимеризации виниль- ных мономеров в присутствии инициирующей системы третичный амин – алкилирующий агент с полимеризацией четвертичных аммониевых солей. Аналогия заключается в идентичности образующихся активных инициирующих центров и механизмов роста и обрыва цепи. При этом в качестве активного роста цепи выступает образующаяся четвертичная аммониевая соль, которая, инициирует полимеризацию винильных мономеров.

The paper examines the polymerization processes of vinyl monomers in the presence of initiating systems amine – alkylating agent, with the formation of quaternary ammonium compounds. Studying the mechanisms of polymerization, a similarity was found between the polymerization of vinyl monomers in the presence of the initiating system tertiary amine – alkylating agent, and the polymerization of quaternary am- monium salts. The analogy lies in the identity of the active initiating centers formed and the mechanisms of chain growth and termination. In this case, the quaternary ammonium salt formed, which initiates the polymerization of vinyl monomers, is an active chain growth agent.

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The authors declare that there are no conflicts of interest present.