<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">ikbgu</journal-id><journal-title-group><journal-title xml:lang="ru">Известия Кабардино-Балкарского государственного университета</journal-title><trans-title-group xml:lang="en"><trans-title>Proceedings of the Kabardino-Balkarian State University</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2221-7789</issn><publisher><publisher-name>Kabardino-Balkarian State University named after Kh. M. Berbekov</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.31143/2221-7789-2025-1-68-72</article-id><article-id custom-type="edn" pub-id-type="custom">BFHMMK</article-id><article-id custom-type="elpub" pub-id-type="custom">ikbgu-29</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Химия</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Chemistry</subject></subj-group></article-categories><title-group><article-title>Влияние образования четвертичных аммониевых солей на полимеризацию некоторых винильных мономеров</article-title><trans-title-group xml:lang="en"><trans-title>Effect of quaternary ammonium salt formation on polymerization of certain vinyl monomers.</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Малкандуев</surname><given-names>Юсуф Ахматович</given-names></name><name name-style="western" xml:lang="en"><surname>Malkanduev</surname><given-names>Yusuf A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Заведующий кафедрой органической химии и высокомолекулярных соединений института математики и естественных наук, доктор химических наук, профессор.</p></bio><email xlink:type="simple">al-aneta@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кокоева</surname><given-names>Анета Ахмедовна</given-names></name><name name-style="western" xml:lang="en"><surname>Kokoeva</surname><given-names>Aneta A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Доцент кафедры органической химии института математики и естественных наук.</p></bio><email xlink:type="simple">al-aneta@mail.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Джалилов</surname><given-names>Абдулахат Турапович</given-names></name><name name-style="western" xml:lang="en"><surname>Jalilov</surname><given-names>Abdulakhat T.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Директор ГУП Ташкентского научно-исследовательского института химической технологии, профессор, доктор химических наук.</p></bio><email xlink:type="simple">al-aneta@mail.ru</email><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Кабардино-Балкарский государственный университет м. Х.М. Бербекова.</institution></aff><aff xml:lang="en"><institution>Kabardino-Balkarian State University m .H.M. Berbekova</institution></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Кабардино-Балкарский государственный университет м. Х.М. Бербекова.</institution></aff><aff xml:lang="en"><institution>Kabardino-Balkarian State University m. H.M. Berbekova</institution></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Ташкентский научно-исследовательский химико-технологический институт.</institution></aff><aff xml:lang="en"><institution>Tashkent Research Institute of Chemical Technology</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>15</day><month>12</month><year>2025</year></pub-date><volume>15</volume><issue>1</issue><fpage>68</fpage><lpage>72</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Малкандуев Ю.А., Кокоева А.А., Джалилов А.Т., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Малкандуев Ю.А., Кокоева А.А., Джалилов А.Т.</copyright-holder><copyright-holder xml:lang="en">Malkanduev Y.A., Kokoeva A.A., Jalilov A.T.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.izvestiakbsu.ru/jour/article/view/29">https://www.izvestiakbsu.ru/jour/article/view/29</self-uri><abstract><p>Проведены исследования реакции полимеризации винильных мономеров в присутст- вии инициирующей системы, образованные как четвертичный аммониевый комплекс на основе амини- рованных полимеров, таких как аминированный пиридином полистирол, триметиламин и полифениле- нэтил. В результате выявлено, что наибольшая скорость полимеризации характерна для гидрофильных мономеров, таких как акриламид. Это обусловлено тем, что полимерный инициатор является водорас- творимым.</p></abstract><trans-abstract xml:lang="en"><p>Studies of the polymerization reaction of vinyl monomers in the presence of an initiating system, formed as a quaternary ammonium complex based on amine polymers, such as pyridine-aminated polystyrene, trimethylamine and polyphenyl-ethyl, have been carried out. As a result, it was found that hydrophilic monomers such as acrylamide had the highest polymerization rate. This is due to the fact that the polymer initiator is water-soluble.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>Полимеризация</kwd><kwd>винильные мономеры</kwd><kwd>аминированные полимеры</kwd><kwd>четвертич- ная аммониевая соль</kwd><kwd>скорость полимеризации</kwd><kwd>водорастворимый инициатор.</kwd></kwd-group><kwd-group xml:lang="en"><kwd>Polymerization</kwd><kwd>vinyl monomers</kwd><kwd>aminated polymers</kwd><kwd>quaternary ammonium salt</kwd><kwd>polymerization rate</kwd><kwd>water-soluble initiator</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Martin D., Cirstea E., Ighigeanu D., Craciun G., Oproiu C., Iovu H., Marin Gh., Iacob N., Nem- tanu M. Polyelectrolytes derived from electron beam-induced polymerization // Vacuum. 2005. V. 77, N 4. Р. 475–484.</mixed-citation><mixed-citation xml:lang="en">Martin D., Cirstea E., Ighigeanu D., Craciun G., Oproiu C., Iovu H., Marin Gh., Iacob N., Nem- tanu M. Polyelectrolytes derived from electron beam-induced polymerization // Vacuum. 2005. V. 77, N 4. Р. 475–484.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Malkanduev Yu.A., Begieva M.B., Kokoeva A.A., Mikitaev M.A., Dzhalilov A.T., Vindizheva M.K. Synthesis and properties of polymers based on n-vinyl-pyrolidone and halogen-containing compounds of acrylic acids // Key Engineering Materials. 2020. V. 869. P. 303–307.</mixed-citation><mixed-citation xml:lang="en">Malkanduev Yu.A., Begieva M.B., Kokoeva A.A., Mikitaev M.A., Dzhalilov A.T., Vindizheva M.K. Synthesis and properties of polymers based on n-vinyl-pyrolidone and halogen-containing compounds of acrylic acids // Key Engineering Materials. 2020. V. 869. P. 303–307.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Kabanov V.A. Topchiyev D.A. Kineticsand mechanism of the radical polymerization of N,N-dialkyl- N,N-diallyl ammonium halides. Review // Polymer Science USSR. 1988. V. 30, N 4. P. 667–679.</mixed-citation><mixed-citation xml:lang="en">Kabanov V.A. Topchiyev D.A. Kineticsand mechanism of the radical polymerization of N,N-dialkyl- N,N-diallyl ammonium halides. Review // Polymer Science USSR. 1988. V. 30, N 4. P. 667–679.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Grishin D.F., Pavlovskaya M.V., Sazonova E.V. Synthesis polyvinylchloride and copolymers based on it in the presence of carbonyl iron complexes // Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2014.</mixed-citation><mixed-citation xml:lang="en">Grishin D.F., Pavlovskaya M.V., Sazonova E.V. Synthesis polyvinylchloride and copolymers based on it in the presence of carbonyl iron complexes // Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2014.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">V. 57, N 8. P. 56–63.</mixed-citation><mixed-citation xml:lang="en">V. 57, N 8. P. 56–63.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Islamova R.M., Puzin Yu.I., Kuznetsov S.I., Muslukhov R.R., Monakov Yu.B. Radical polymeriza- tion of methyl methacrylate in the presence of a peroxide initiator, ferrocene and zirconocendichloride // Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2007. V. 50, N 2. P. 62–65.</mixed-citation><mixed-citation xml:lang="en">Islamova R.M., Puzin Yu.I., Kuznetsov S.I., Muslukhov R.R., Monakov Yu.B. Radical polymeriza- tion of methyl methacrylate in the presence of a peroxide initiator, ferrocene and zirconocendichloride // Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2007. V. 50, N 2. P. 62–65.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang K., Monteiroa M.J., Jia Z. Stable organic radical polymers: synthesis and applications // Polym. Chem. 2016. V. 7. P. 5589–5614.</mixed-citation><mixed-citation xml:lang="en">Zhang K., Monteiroa M.J., Jia Z. Stable organic radical polymers: synthesis and applications // Polym. Chem. 2016. V. 7. P. 5589–5614.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Aqil M., Aqil A., Ouahib F., Detrembleur C., Jerome C., El Idrissi A. A novel synthetic route toward a PTA as active materials for organic radical batteries // International Renewable and Sustainable Energy Con- ference (IRSEC). Marrakech, 2016. P. 961–965.</mixed-citation><mixed-citation xml:lang="en">Aqil M., Aqil A., Ouahib F., Detrembleur C., Jerome C., El Idrissi A. A novel synthetic route toward a PTA as active materials for organic radical batteries // International Renewable and Sustainable Energy Con- ference (IRSEC). Marrakech, 2016. P. 961–965.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Weber A.Z., Mench M.M., Meyers J.P., Ross P.N., Gostick J.T., Liu Q. Redox flow batteries: a review //</mixed-citation><mixed-citation xml:lang="en">Weber A.Z., Mench M.M., Meyers J.P., Ross P.N., Gostick J.T., Liu Q. Redox flow batteries: a review //</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">J. Appl. Electrochem. 2011. V. 41, N 10. P. 1137–1164.</mixed-citation><mixed-citation xml:lang="en">J. Appl. Electrochem. 2011. V. 41, N 10. P. 1137–1164.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Safaev U.A., Khodjaev Sh.F., Safaev F.U. Synthesis and use of polymeric quaternary salt of di- methylaminoethylmethacrylate with allyl chloroacetate // European Applied Sciences. Stuttgart, 2015. N 7. Р. 70–73.</mixed-citation><mixed-citation xml:lang="en">Safaev U.A., Khodjaev Sh.F., Safaev F.U. Synthesis and use of polymeric quaternary salt of di- methylaminoethylmethacrylate with allyl chloroacetate // European Applied Sciences. Stuttgart, 2015. N 7. Р. 70–73.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Safronova E.Yu., Yaroslavtsev A.B. Prospects of practical application of hybrid membranes // Petroleum Chemistry. 2016. V. 56, N 4. P. 281–293.</mixed-citation><mixed-citation xml:lang="en">Safronova E.Yu., Yaroslavtsev A.B. Prospects of practical application of hybrid membranes // Petroleum Chemistry. 2016. V. 56, N 4. P. 281–293.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Liguori F., Coiai S., Passaglia E., Barbaro P. Strong Cation Exchange with Innocence: Synthesis and Characterization of Borate Containing Resins and Macroporous Monoliths // Macromolecules. 2013. V. 46, N 14. P. 5423–5433.</mixed-citation><mixed-citation xml:lang="en">Liguori F., Coiai S., Passaglia E., Barbaro P. Strong Cation Exchange with Innocence: Synthesis and Characterization of Borate Containing Resins and Macroporous Monoliths // Macromolecules. 2013. V. 46, N 14. P. 5423–5433.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Moiseev S.K., Chaschin I.S., Godovikova M.I., Dolgushin F.M., Khokhlov A.R. Sulfonium salts de- rived from α-ferrocenylvinyl cation in situ generated in sc-CO2 from ethynylferrocene by nafion film // The Journal of Supercritical Fluids. 2019. Р. 152.</mixed-citation><mixed-citation xml:lang="en">Moiseev S.K., Chaschin I.S., Godovikova M.I., Dolgushin F.M., Khokhlov A.R. Sulfonium salts de- rived from α-ferrocenylvinyl cation in situ generated in sc-CO2 from ethynylferrocene by nafion film // The Journal of Supercritical Fluids. 2019. Р. 152.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang K., Monteiroa M.J., Jia Z. Stable organic radical polymers: synthesis and applications // Polym. Chem. 2016. V. 7. P. 5589–5614.</mixed-citation><mixed-citation xml:lang="en">Zhang K., Monteiroa M.J., Jia Z. Stable organic radical polymers: synthesis and applications // Polym. Chem. 2016. V. 7. P. 5589–5614.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
