ikbguИзвестия Кабардино-Балкарского государственного университетаProceedings of the Kabardino-Balkarian State University2221-7789Kabardino-Balkarian State University named after Kh. M. Berbekov10.31143/2221-7789-2024-1-53-57YIPXGRikbgu-78Research ArticleХимияChemistryСТРУКТУРООБРАЗОВАНИЕ ЭЛЕКТРОПРОВОДЯЩИХ ПОЛИАНИЛИНА И ТЕТРААНИЛИНА В МОНОМОЛЕКУЛЯРНЫХ СЛОЯХ НА ПОВЕРХНОСТИ ЖИДКОСТИSTRUCTURE FORMATION OF ELECTRICALLY CONDUCTIVE POLYANILINE AND TETRAANILINE IN MONOMOLECULAR LAYERS ON A LIQUID SURFACEМалаховаЮ. Н.MalakhovaYu. N.j.malakhova@mail.ruБартеневаВ. М.BartenevaV. M.j.malakhova@mail.ruСтупниковА. А.StupnikovA. A.j.malakhova@mail.ruЯгудаеваЕ. Ю.YagudaevaE. Yu.j.malakhova@mail.ruЗубовВ. П.ZubovV. P.j.malakhova@mail.ruНациональный исследовательский центр «Курчатовский институт»; МИРЭА – Российский технологический университетNational Research Center «Kurchatov Institute»; MIREA – Russian Technological UniversityМИРЭА – Российский технологический университетMIREA – Russian Technological UniversityНациональный исследовательский центр «Курчатовский институт»; Институт биоорганической химии им. Ак. М.М. Шемякина и Ю.А. Овчинникова РАНNational Research Center «Kurchatov Institute»Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry RASRussian FederationМИРЭА – Российский технологический университет; Институт биоорганической химии им. Ак. М.М. Шемякина и Ю.А. Овчинникова РАНMIREA – Russian Technological University; Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry RAS2024300320241415357Copyright © Малахова Ю.Н., Бартенева В.М., Ступников А.А., Ягудаева Е.Ю., Зубов В.П., 20242024Малахова Ю.Н., Бартенева В.М., Ступников А.А., Ягудаева Е.Ю., Зубов В.П.Malakhova Y.N., Barteneva V.M., Stupnikov A.A., Yagudaeva E.Y., Zubov V.P.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.izvestiakbsu.ru/jour/article/view/78

В работе установлено, что эмеральдиновое основание полианилина формирует аморфный ленгмюровский слой, тогда как тетраанилина – кристаллический, соответствующий кристаллической решетке ЭО-II. Напротив, эмеральдиновая соль полианилина, протонированная соляной кислотой, формирует кристаллическую тонкую пленку, соответствующую кристаллической решетке ЭС-I, тогда как тетраанилина, протонированная камфорсульфоновой кислотой – аморфный мономолекулярный слой.

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The authors declare that there are no conflicts of interest present.