ikbguИзвестия Кабардино-Балкарского государственного университетаProceedings of the Kabardino-Balkarian State University2221-7789Kabardino-Balkarian State University named after Kh. M. Berbekov10.31143/2221-7789-2024-1-63-67APJAVQikbgu-80Research ArticleХимияChemistryСИНТЕЗ ПОЛИАНИЛИНА, ДОПИРОВАННОГО ТЕРЕФТАЛЕВОЙ КИСЛОТОЙ, И СОЗДАНИЕ ПОЛНОСТЬЮ ОРГАНИЧЕСКОГО МЕМРИСТОРА НА ЕГО ОСНОВЕSYNTHESIS OF POLYANILINE DOPED WITH TEROHATLIC ACID AND THE CREATION OF A FULLY ORGANIC MEMRISTOR ON ITS BASISМельниченкоВ. Э.MelnichenkoV. E.vasiliyerikovich@gmail.comБудаевА. В.KudryavtsevaT. N.vasiliyerikovich@gmail.comКоротковскийВ. И.BudaevA. V.vasiliyerikovich@gmail.comКудрявцеваТ. Н.KorotkovskiiV. I.vasiliyerikovich@gmail.comЕмельяновН. А.EmelianovN. A.vasiliyerikovich@gmail.comСтупаковаД. А.StupakovaD. A.vasiliyerikovich@gmail.comКурский государственный университетKursk State University2024300320241416367Copyright © Мельниченко В.Э., Будаев А.В., Коротковский В.И., Кудрявцева Т.Н., Емельянов Н.А., Ступакова Д.А., 20242024Мельниченко В.Э., Будаев А.В., Коротковский В.И., Кудрявцева Т.Н., Емельянов Н.А., Ступакова Д.А.Melnichenko V.E., Kudryavtseva T.N., Budaev A.V., Korotkovskii V.I., Emelianov N.A., Stupakova D.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.izvestiakbsu.ru/jour/article/view/80

Был синтезирован полианилин в форме эмеральдин соли терефталевой кислоты (PANI-ES (ТФК)). Методом УФ/видимой спектроскопии показано, что полученный PANI-ES (ТФК) имеет значение ширины оптической запрещенной зоны равное 1,59 эВ. Четырехзондовым методом определено значение удельной проводимости полученного полимера, которое составило 1,34 см/см. На основе PANIES (ТФК) было собрано мемристивное электрическое устройство, которое показало бóльшую стабильность в процессе эксплуатации, по сравнению с устройством на основе PANI-ES (HCl).

Polyaniline was synthesized in the form of emeraldine salt of terephthalic acid (PANI-ES (TPA)). It was shown by UV/vis spectroscopy that the obtained PANI-ES (TPA) has an optical band gap value of 1.59 eV. The conductivity value of the resulting polymer was determined by the four-probe method, which amounted to 1.34/cm. Based on PANI-ES (TPA), a memristive electrical device was assembled, which showed greater stability during operation, compared to a device based on PANI-ES (HCl).

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The authors declare that there are no conflicts of interest present.