FEATURES OF CURING 1,3-DINITRILE OXIDE-2,4,6-TRIETHYLBENZOLE POLYMER COMPOSITIONS WITH HIGH UNSATURATED POLYMERS
https://doi.org/10.31143/2221-7789-2024-2-98-102
EDN: KFYJMC
Abstract
The results of studies on the curing of 1,3-dinitrile oxide-2,4,6-triethylbenzole (TON-2) binders based on polymers with high unsaturated content are presented. It is shown that the crosslinking rate, survivability time and gelation are similar for butadiene, acrylonitrile, tetrazole polymers and copolymers. Methods for regulating the technological characteristics of binders and compositions using molecular complexes and TON-2 co- crystallizers are proposed.
References
1. Patent US № 8507610 B2. 2013. Modified polymer material modified by nitrile oxide, and produc- tion method thereof / Seo A., Imai H., Iwase N. 2013.
2. Popok V.N., Khmelev V.N. Mixing condensed chemical fuels based on ammonium nitrate. Principles of layout and properties. Biysk: Publishing house of Alt. state. tenh. un-ta, 2014. 222 p.
3. Popok V.N., Fedorishcheva N.A. Molecular complexes and interaction of 1,3-dinitroxy-2,4,6-triethylbenzene and stabilizers of chemical resistance of mixed energy materials // Butlerov Communications. 2015. Vol. 43, No. 7. Pp. 48–63.
4. Huang M.R., Li X.G., Li S.X. Resultful synthesis of polyvinyltetrazole from polyacrylonitrile // Reac- tive and Functional Polymers. 2004. V. 59. P. 53–61.
5. Belousov A.M., Paznikov E.A., Petrova G.Ya. Kalmykov P.I. Research of the low-temperature process of the curing of poly-N-methylallyl-5-vinyltetrazole // Journal of Applied Chemistry. 2003. V. 76, No. 7. P. 1197–1199.
6. Popok V.N., Pivovarov Yu.A., and Bychin N.V. Influence of micro- and nano-dispersed aluminum powders and passivating additives on the rheokinetics of 1,3-dinitroso-2,4,6-triethylbenzene curing and the mechanical characteristics of the compositions
Review
For citations:
Popok V.N. FEATURES OF CURING 1,3-DINITRILE OXIDE-2,4,6-TRIETHYLBENZOLE POLYMER COMPOSITIONS WITH HIGH UNSATURATED POLYMERS. Proceedings of the Kabardino-Balkarian State University. 2024;14(2):98-102. (In Russ.) https://doi.org/10.31143/2221-7789-2024-2-98-102. EDN: KFYJMC
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