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POLYPERFLUOROOCTYLMETHYLSILOXANE-POLYDECYLMETHYLSILOXANE COPOLYMER: SYNTHESIS AND PROPERTIES

https://doi.org/10.31143/2221-7789-2024-2-103-108

EDN: RACZJV

Abstract

The possibility of the introduction of perfluorooctene-1 into polymethylhydrosiloxane by hydrosilylation reaction as well as the synthesis of cross-linked copolymers polydecylmethylsiloxane-polyperfluorooctylmethylsiloxane (PDec-PFOMS) was confirmed for the first time. The quantitative substitution of the Si-H bond in PDec-PFOMS was determined from NMR data. Thermal properties and surface tension against water and n- butanol were investigated. It is shown that an increase in the content of fluorine-containing groups leads to an increase in the wetting angle for n-butanol.

About the Authors

T. N. Rokhmanka
Институт нефтехимического синтеза им. А.В. Топчиева Российской Академии наук
Russian Federation


G. S. Golubev
Институт нефтехимического синтеза им. А.В. Топчиева Российской Академии наук
Russian Federation


V. P. Vasilevsky
Институт нефтехимического синтеза им. А.В. Топчиева Российской Академии наук
Russian Federation


E. A. Grushevenko
Институт нефтехимического синтеза им. А.В. Топчиева Российской Академии наук
Russian Federation


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Review

For citations:


Rokhmanka T.N., Golubev G.S., Vasilevsky V.P., Grushevenko E.A. POLYPERFLUOROOCTYLMETHYLSILOXANE-POLYDECYLMETHYLSILOXANE COPOLYMER: SYNTHESIS AND PROPERTIES. Proceedings of the Kabardino-Balkarian State University. 2024;14(2):103-108. (In Russ.) https://doi.org/10.31143/2221-7789-2024-2-103-108. EDN: RACZJV

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