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STUDY OF THE POSSIBILITY OF CHEMICAL MODIFICATION OF AROMATIC BLOCK POLYESTERS WITH CYCLOHEXYLPHOSPHONIC ACID DICHLOROANHYDRIDE

https://doi.org/10.31143/2221-7789-2024-4-85-89

EDN: IDUOOA

Abstract

Various monomers, in particular dichlorides of organic phosphorus acids, are used to obtain high-molecular compounds containing organophosphorus fragments in the main chain. It is known that organophosphorus polymers from phosphorus acid dichlorides with high molecular weights cannot be obtained due to the delocalization of the electron density on the phosphorus atom after one chlorine atom has entered the reaction, resulting in the passivation of the second chlorine atom.

About the Authors

A. Kh. Shaov
Kabardino-Balkarian State University
Russian Federation


T. A. Borukaev
Kabardino-Balkarian State University
Russian Federation


A. N, Beslaneeva
Kabardino-Balkarian State University
Russian Federation


K., - Nzhekva
Kabardino-Balkarian State University
Russian Federation


A. A. Daurov
Kabardino-Balkarian State University
Russian Federation


References

1. Гефтер Е.Л. Фосфорорганические мономеры и полимеры. М.: Академия наук СССР, 1960. 287 с.

2. Соборовский Л.З., Зиновьев Ю.М. Дихлорангидрид циклогексилфосфоновой кислоты (циклогексил- дихлорфосфиноксид) // Методы получения химических реактивов и препаратов. 1965. № 12. С. 66–67.


Gefter E.L. Organophosphorus monomers and polymers. M.: USSR Academy of Sciences, 1960. 287 pp.

Soborovsky L.Z., Zinoviev Yu.M. Cyclohexylphosphonic acid dichloride (cyclohexyl-dichlorophosphine oxide )//Methods for the production of chemicals and preparations. 1965. № 12. S. 66-67.

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For citations:


Shaov A.Kh., Borukaev T.A., Beslaneeva A.N., Nzhekva K.-., Daurov A.A. STUDY OF THE POSSIBILITY OF CHEMICAL MODIFICATION OF AROMATIC BLOCK POLYESTERS WITH CYCLOHEXYLPHOSPHONIC ACID DICHLOROANHYDRIDE. Proceedings of the Kabardino-Balkarian State University. 2024;14(4):85-89. (In Russ.) https://doi.org/10.31143/2221-7789-2024-4-85-89. EDN: IDUOOA

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ISSN 2221-7789 (Print)