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THEORETICAL ANALYSIS OF FORMATION OF INTERPHASE REGIONS IN DISPERSED-FILLED NANOCOMPOSITES BASED ON STYRENE-BUTADIENE RUBBER (SBR)

https://doi.org/10.31143/2221-7789-2023-1-05-09

EDN: IVOIPZ

Abstract

The effect of diffusion processes on the formation of interfacial regions in nanocomposites based on styrene-butadiene rubber (SBR) was studied: SBR/carbon black (SBR/TU), SBR/microshungite, and SBR/nanoshungite. A theoretical analysis of the formation of interfacial regions in particulate-filled polymer nanocomposites has been carried out within the framework of the fractal and percolation concepts. A detailed quantitative description of the structure and properties of both interfacial regions and the nanocomposite as a whole is proposed.

About the Authors

Kh. Sh Yakh'yaeva
Dagestan State Agrarian University, named after M.M. Dzhambulatov
Russian Federation


S. M. Orakova
Dagestan State Agrarian University, named after M.M. Dzhambulatov Kh.I. Amirkhanov Institute of Physics of the Russian Academy of Sciences
Russian Federation


S. A. Jamalova
Dagestan State University of National Economy
Russian Federation


References

1. Wake W.C. Adhesion and Formulation of Adhesives. London-New York: Applied Science Publish- ers, 1982. 332 p.

2. Козлов Г.В., Яновский Ю.Г. Межфазная адгезия в дисперсно-наполненных эластомерных на- нокомпозитах // Нанотехнологии: Наука и производство, 2011. № 5. С. 64–70.

3. Kozlov G.V., Yanovskii Yu.G., Zaikov G.E. The modern experimental and theoretical analysis meth- ods of particulate filled nanocomposites structure // Polymer Research J. 2012. V. 6, N 1. P. 47–73.

4. Meakin P. Diffusion-limited deposition on fibers and surfaces // Phys. Rev. A. 1983. V. 27, N 5.

5. P. 2616–2623.

6. Meakin P. Diffusion-controlled deposition on surfaces: cluster size distribution, interface exponents and other properties // Phys. Rev. B. 1984. V. 30, N 8. P. 4207–4214.

7. Микитаев А.К., Козлов Г.В., Заиков Г.Е. Полимерные нанокомпозиты: многообразие струк- турных форм и приложений. М.: Наука, 2009. 278 с.

8. Козлов Г.В., Яновский Ю.Г., Карнет Ю.Н. Структура и свойства дисперсно-наполненных по- лимерных композитов: фрактальный анализ. М.: Альянстрансатом, 2008. 363 с.

9.

10. Aharoni S. Correlation between chain parameters and failure characteristics of polymers below their glass transition temperature // Macromolecules. 1985. V. 18, N 12. P. 2624–2630.

11. Будтов В.П. Физическая химия растворов полимеров. СПб.: Химия, 1992. 384 с.

12. Шогенов В.Н., Козлов Г.В., Микитаев А.К. Прогнозирование механического поведения, структуры и свойств пленочных полимерных образцов при квазистатическом растяжении // Поликон- денсационные реакции и полимеры. Избранные труды. Нальчик: КБГУ, 2007. С. 252–270.

13. Yanovskii Yu.G, Kozlov G.V., Yakh’yaeva Kh.Sh., Richert J., Zaikov G.E. Formation mechanism finter facial regions in particulate – filled elastomeric nanocomposites // Characterization and Development of Novel Materials. 2015. V. 7, N 1. P. 1–11.

14. Козлов Г.В., Овчаренко Е.Н., Микитаев А.К. Структура аморфного состояния полимеров. М.: РХТУ им. Д.И. Менделеева, 2009. 392 с.

15. Oliver W.C., Pharr G.M. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments//J. Mater. Res. 1992. V. 7, N 6. P. 1564–1583.

16. Kozlov G.V., Yanovsky Yu.G., Zaikov G.E. Structure and Properties of Particulate-Filled Polymer Composites: the Fractal Analysis. New York: Nova Science Publishers, Inc., 2010. 282 p.

17. Kubat J., Rigdahl M., Welander M. Characterization of interfacial interactions in high density poly- ethylene filled with glass spheres using dynamic-mechanical analysis // Appl. Polymer Sci. 1990. V. 39, N 5. P. 1527–1539.

18. Баланкин А.С. Синергетика деформируемого тела. М.: Министерство обороны СССР, 1991.

19. с.


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For citations:


Yakh'yaeva Kh.Sh., Orakova S.M., Jamalova S.A. THEORETICAL ANALYSIS OF FORMATION OF INTERPHASE REGIONS IN DISPERSED-FILLED NANOCOMPOSITES BASED ON STYRENE-BUTADIENE RUBBER (SBR). Proceedings of the Kabardino-Balkarian State University. 2023;13(1):5-9. (In Russ.) https://doi.org/10.31143/2221-7789-2023-1-05-09. EDN: IVOIPZ

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ISSN 2221-7789 (Print)