THEORETICAL ANALYSIS OF FORMATION OF INTERPHASE REGIONS IN DISPERSED-FILLED NANOCOMPOSITES BASED ON STYRENE-BUTADIENE RUBBER (SBR)
https://doi.org/10.31143/2221-7789-2023-1-05-09
EDN: IVOIPZ
Abstract
The effect of diffusion processes on the formation of interfacial regions in nanocomposites based on styrene-butadiene rubber (SBR) was studied: SBR/carbon black (SBR/TU), SBR/microshungite, and SBR/nanoshungite. A theoretical analysis of the formation of interfacial regions in particulate-filled polymer nanocomposites has been carried out within the framework of the fractal and percolation concepts. A detailed quantitative description of the structure and properties of both interfacial regions and the nanocomposite as a whole is proposed.
About the Authors
Kh. Sh Yakh'yaevaRussian Federation
S. M. Orakova
Russian Federation
S. A. Jamalova
Russian Federation
References
1. Wake W.C. Adhesion and Formulation of Adhesives. London-New York: Applied Science Publish- ers, 1982. 332 p.
2. Козлов Г.В., Яновский Ю.Г. Межфазная адгезия в дисперсно-наполненных эластомерных на- нокомпозитах // Нанотехнологии: Наука и производство, 2011. № 5. С. 64–70.
3. Kozlov G.V., Yanovskii Yu.G., Zaikov G.E. The modern experimental and theoretical analysis meth- ods of particulate filled nanocomposites structure // Polymer Research J. 2012. V. 6, N 1. P. 47–73.
4. Meakin P. Diffusion-limited deposition on fibers and surfaces // Phys. Rev. A. 1983. V. 27, N 5.
5. P. 2616–2623.
6. Meakin P. Diffusion-controlled deposition on surfaces: cluster size distribution, interface exponents and other properties // Phys. Rev. B. 1984. V. 30, N 8. P. 4207–4214.
7. Микитаев А.К., Козлов Г.В., Заиков Г.Е. Полимерные нанокомпозиты: многообразие струк- турных форм и приложений. М.: Наука, 2009. 278 с.
8. Козлов Г.В., Яновский Ю.Г., Карнет Ю.Н. Структура и свойства дисперсно-наполненных по- лимерных композитов: фрактальный анализ. М.: Альянстрансатом, 2008. 363 с.
9.
10. Aharoni S. Correlation between chain parameters and failure characteristics of polymers below their glass transition temperature // Macromolecules. 1985. V. 18, N 12. P. 2624–2630.
11. Будтов В.П. Физическая химия растворов полимеров. СПб.: Химия, 1992. 384 с.
12. Шогенов В.Н., Козлов Г.В., Микитаев А.К. Прогнозирование механического поведения, структуры и свойств пленочных полимерных образцов при квазистатическом растяжении // Поликон- денсационные реакции и полимеры. Избранные труды. Нальчик: КБГУ, 2007. С. 252–270.
13. Yanovskii Yu.G, Kozlov G.V., Yakh’yaeva Kh.Sh., Richert J., Zaikov G.E. Formation mechanism finter facial regions in particulate – filled elastomeric nanocomposites // Characterization and Development of Novel Materials. 2015. V. 7, N 1. P. 1–11.
14. Козлов Г.В., Овчаренко Е.Н., Микитаев А.К. Структура аморфного состояния полимеров. М.: РХТУ им. Д.И. Менделеева, 2009. 392 с.
15. Oliver W.C., Pharr G.M. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments//J. Mater. Res. 1992. V. 7, N 6. P. 1564–1583.
16. Kozlov G.V., Yanovsky Yu.G., Zaikov G.E. Structure and Properties of Particulate-Filled Polymer Composites: the Fractal Analysis. New York: Nova Science Publishers, Inc., 2010. 282 p.
17. Kubat J., Rigdahl M., Welander M. Characterization of interfacial interactions in high density poly- ethylene filled with glass spheres using dynamic-mechanical analysis // Appl. Polymer Sci. 1990. V. 39, N 5. P. 1527–1539.
18. Баланкин А.С. Синергетика деформируемого тела. М.: Министерство обороны СССР, 1991.
19. с.
Review
For citations:
Yakh'yaeva Kh.Sh., Orakova S.M., Jamalova S.A. THEORETICAL ANALYSIS OF FORMATION OF INTERPHASE REGIONS IN DISPERSED-FILLED NANOCOMPOSITES BASED ON STYRENE-BUTADIENE RUBBER (SBR). Proceedings of the Kabardino-Balkarian State University. 2023;13(1):5-9. (In Russ.) https://doi.org/10.31143/2221-7789-2023-1-05-09. EDN: IVOIPZ
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