Triptycenediol-2,5 polycarbonates
https://doi.org/10.31143/2221-7789-2026-2-95-99
EDN: KSYYDK
Abstract
The synthesis and properties of polycarbonate and copolycarbonates of trypticenediol-2,5 are considered. The mechanical properties of mixtures of industrial polycarbonate and polycarbonate of trypticenediol-2,5 are investigated. It is established that polycarbonate and copolycarbonates of trypticenediol-2,5 have higher glass transition temperatures and improved chemical resistance compared to polycarbonate of 2,2-di-(4-oxyphenyl)-propane. It has also been shown that the presence of trypticene units improves the mechanical properties of the mixtures compared to industrial polycarbonate
About the Authors
Konstantin B. TemiraevRussian Federation
Marina V. Khudoyan
Russian Federation
Irina V. Mishenina
Russian Federation
Gennady B. Shustov
Russian Federation
Safiyat M. Balaeva
Russian Federation
Elina V. Khakyasheva
Russian Federation
References
1. Sweileh B., Al-Hiari Yu., Kailani M.H., Mohammed H.A.Y. Synthesis and characterization of polycarbonates by melt phase interchange reactions of alkilene and arylene diacetates with alkilene and arylene diphenyl dicarbonates // Molecules. 2010. V. 15. P. 3661.
2. Anashkin D.O. Synthesis and Properties Study of New Polycarbonate-Siloxanes: PhD Thesis in Chemistry. Moscow, 2006. 109 p.
3. Ning W., Zhu W., Zhang B., Li C., Liu C., Wang D. Effect of chemical structure of polycarbonates on entanglement specing // Chinese journal of polymer science. 2012. V. 30. P. 343.
4. Zapornikov V.A., Osipchik V.S., Redkina A.A. Influence of Modifying Additives on the Processability and Physical and Mechanical Properties of Polycarbonate. Izvestiya Vysshikh Uchebnykh Zavedeniy. Seriya Khimiya i Khimicheskaya Tekhnologiya = News of higher educational institutions. Series: Chemistry and chemical technology. 2014;57(4):65.
5. Bartlett P.D., Ryan M.J., Cohen S.G. Triptycene (9,10-o-benzenoanthracene) // J. Amer. Soc. 1942.
6. V. 64. P. 2649–2653.
7. Kozlov G.V., Keharsaeva E.R., Shogenov V.N., Beriketov A.S., Kharaev A.M., Mikitaev A.K. Correlation between deformation of polymer films and molecular parameters of polymers. Vysokomolekulyarnyye soyedineniya В = High-molecular compounds. Series B.1986;28(1):3.
8. Carta M., Croad M., Malpass-Evans R., Jansen J.C., Bernardo P., Claricia G., Friss K., Lanc M., McKeown N.B. Triptycene induced enhancement of Membrane gas selectivity for microporous Trogers base polymers // Advances Materials. 2014. V. 26, N 21. P. 3526.
9. Bezzu G.C., Fuoko A., Esposito E., Monteleone M., Longo M., Jansen J.C., Nichol G.S., McKeown
10. N.B. Ultrapermeable polymers of intrinsic microporosity (PIMs) containing spirocyclic units with fused triptycenes // Advanced Funct. Materials. 2021. V. 31, N 37. P. 2104474.
11. Temiraev K.B., Khudoyan M.V., Mishenina I.V., Shustov G.B., Balaeva S.M., Shetov R.A. Aromatic polyethers of triptycenediol-2,5. Izvestiya Kabardino-Balkarskogo gosudarstvennogo universiteta = Proseeding of the Kabardino-Balkarian State University. 2023;13(2):80.
12. Boyles D.A., Filipova T.S., Bendler J.T. Aromatic copolycarbonates of bis-phenol A and triptycene-1,4-hydroquinone // Polymer Preprints. 2007. V. 48, N 1. P. 352.
13. Smirnova O.V., Mikitaev A.K., Tsaloeva N.G. Copolycarbonates based on triptycenediol-2,5 and bisphenol A. In book: Polikondensatsionnyye protsessy i polimery = Polycondensation processes and polymers. Nalchik, 1986. P. 182.
14. Tsui N.T., Yong Y., Mulliken A.D., Lokman T., Boyce M.C., Swager T.M., Thomas E.L. Enhancement to rate-dependent mechanical behavior of polycarbonate by incorporation of triptycenes // Polymer. 2008.V. 49. P. 4703.
Review
For citations:
Temiraev K.B., Khudoyan M.V., Mishenina I.V., Shustov G.B., Balaeva S.M., Khakyasheva E.V. Triptycenediol-2,5 polycarbonates. Proceedings of the Kabardino-Balkarian State University. 2026;16(2):95-99. (In Russ.) https://doi.org/10.31143/2221-7789-2026-2-95-99. EDN: KSYYDK
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