PROCESSES OF ELECTRON AND ION TRANSFER ON INTERFACE BOUNDARY COMPLEX OXIDE OF TRANSIENT METAL – LIQUID ELECTROLYTE
https://doi.org/10.31143/2221-7789-2024-2-10-14
EDN: GXXZOA
Abstract
The results of the measurements of the volt-ampere and volt-estance characteristics for the changing nature of interaction between the amorphous thin films of complex tungsten oxides (tungsten oxide bronzes, TOB), as well as the monocrystals of TOB, and electromagnetic radiation have been presented. The nature of the al- teration of such interaction is determined by the temperature of the substrate at vacuum condensation in case of amorphous thin films and by the influence on the structure of the near-surface layer in case of monocrystals. The distinguishing from the general model of the physical processes occurring in the near-surface areas of the given oxides and on the boundary TOB – liquid electrolyte has been given.
About the Authors
R. A. Musukov
Kabardino-Balkarian State University
Russian Federation
Russian Federation
B. M. Khubolov
Kabardino-Balkarian State University
Russian Federation
Russian Federation
A. M. Bagov
Kabardino-Balkarian State University
Russian Federation
Russian Federation
Zh. Zh. Zhaboev
Kabardino-Balkarian State University
Russian Federation
Russian Federation
I. R. Makhov
Kabardino-Balkarian State University
Russian Federation
Russian Federation
References
1. Khulobov B.M., Podlinov V.P. Influence of oxygen vacancies on transport processes in amorphous thin films of complex tungsten oxides // Surface. X-ray, synchrotron, and neutron research. 2004. No. 9. Pp. 86–90.
2. Weber M.F., Shanks H.R., Bevolo A.J., Danielson G.C. Surface properties of sodium tungsten bronzes // J. Electrochem. Soc. 1980. V. 127. P. 329–333.
3. Randin J.P. Alternating current impedance characteristics of reduced and oxidised sodium-tungsten bronze electrodes // Electrochim. Acta. 1974. V. 19. P. 87.
4. Kao K., Huang V. Electron Transfer in Solids. Moscow: Mir, 1984. Part 1. 352 p.
5. Gokhshtein A.Ya. Surface Tension of Solids and Adsorption. Moscow: Nauka, 1976. 400 p.
6. Dogonadze R.R., Kuznetsov A.M. Kinetics and Catalysis. Moscow: Mir, 1978. Vol. 5. 224 p.
7. Akhkubekov A.A., Savintsev A.P., Bagov A.M. Kinetics of the formation of a melt resulting from contact melting under conditions of the retardation effect of electrotransfer // Melts. 2005. No. 1. Pp. 54–58.
8. Bagov A.M., Akhkubekov A.A., Akhkubekova S.N., Kumukova T.Zh. The effect of doping of lead with lithium and zinc with strontium on the kinetics and phase formation in a number of low-melting eutectic systens user in electronics and heat-transfer agents // Nano Hybrids and Composites. 2020. V. 28. Р. 26–30.
9. Akhkubekov A.A., Savintsev A.P., Bagov A.M. Influence of electrotransport on crystallization and macroscopic flow during contact melting of metals // Metals. 2004. No. 4. Pp. 33–36.
10. Khubolov B.M., Arbuzov V.Ya. Investigation of the near-surface layer of sodium-tungsten bronze single crystals using protonography and nuclear reactions // Bulletin of KBGU. Series "Physical Sciences". 2002. No. 7. Pp. 23–25.
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For citations:
Musukov R.A., Khubolov B.M., Bagov A.M., Zhaboev Zh.Zh., Makhov I.R. PROCESSES OF ELECTRON AND ION TRANSFER ON INTERFACE BOUNDARY COMPLEX OXIDE OF TRANSIENT METAL – LIQUID ELECTROLYTE. Proceedings of the Kabardino-Balkarian State University. 2024;14(2):10-14. (In Russ.) https://doi.org/10.31143/2221-7789-2024-2-10-14. EDN: GXXZOA
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