THE ROLE OF FILLER ANISOTROPY IN FORMATION OF POLYMER COMPOSITES PROPERTIES
https://doi.org/10.31143/2221-7789-2024-2-113-118
EDN: QHVMBE
Abstract
It has been shown that the anisotropy degree of filler in polymer matrix, essentially influencing on composites properties, is structural factor. This factor is defined by composite components affinity within the frameworks of fractal analysis. The composite components affinity defines unequivocally such important properties of these materials as, by example, the filler efficiency as reinforcing element, its real elastic modulus and another things. The number of methods was proposed, allowing to change purposefully anisotropy degree in process of composites preparation.
About the Authors
D. S. Tochiev
Ingush State University
Russian Federation
Russian Federation
Kh. Kh. Sapaev
Chechen State University
Russian Federation
Russian Federation
V. V. Davydova
Russian State University of Tourism and Service
Russian Federation
Russian Federation
I. V. Dolbin
Kabardino-Balkarian State University
Russian Federation
Russian Federation
References
1. Fornes T.D., Paul D.R. Modeling properties of nylon 6/clay nanocomposites using composite theories // Polymer. 2003. V. 44, N 17. P. 4993–5013.
2. Kozlov G.V., Dolbin I.V. Influence of the Affinity of the Components of the Polymer/Graphene Nanocomposite Structure on Its Properties // Surface. X-ray, Synchrotron, and Neutron Research. 2022, No. 1. Pp. 58–62.
3. Kozlov G.V., Dolbin I.V. Influence of the Affinity of the Components of the Polymer/Carbon Nanotube Nanocomposite Structure on Its Properties // Surface Physics and Materials Protection. 2022. Vol. 58, No. 5. Pp. 521–525.
4. Patrushev L.I. Artificial Genetic Systems. Vol. 1. Genetic and Protein Engineering. Moscow: Nauka, 2004. 526 p.
5. Šupova M., Martynkova G.S., Barabaszova K. Effect of nanofiller dispersion in polymer matrices: a review // Sci. Advanced Mater. 2011. V. 3, N 1. P. 1–25.
6. Atlukhanova L.B., Kozlov G.V. Physical Chemistry of Polymer-Carbon Nanotube Nanocomposites. Moscow: Sputnik + Publishing House, 2020. 292 p.
7. Kozlov G.V., Dolbin I.V. Features of the filler aggregation process in polymer-carbon nanotube nanocomposites // Applied Mechanics and Technical Physics. 2020. Vol. 61, No. 2. Pp. 125–129.
8. Coleman J.N., Khan U., Blau W.J., Gun’ko Yu.K. Small but strong: a review of the mechanical prop- erties of carbon nanotube-polymer composites // Carbon. 2006. V. 44, N 6. P. 1624–1652.
9. Coleman J.N., Cadek M., Pyan K.P., Fonseca A., Nady J.B., Blau W.J., Ferreira M.S. Reinforce- ment of polymers with carbon nanotubes: the role of an ordered polymer interfacial region. Experiment and modeling // Polymer. 2006. V. 47, N 23. P. 8556–8561.
10. Kozlov G.V., Rizvanova P.G., Dolbin I.V., Magomedov G.M. Determination of the Elastic Modulus of a Nanoparticle Filler in a Polymer Nanocomposite Matrix // Izvestiya VUZov. Physics. 2019. Vol. 62, No. 1. Pp. 112–116.
11. Dolbin I.V., Magomedov G.M., Kozlov G.V. Influence of the Polymer Matrix Stiffness on the Effectiveness of Carbon Nanotube Reinforcement of Nanocomposites // Izvestiya VUZov. Physics. 2022. Vol. 65, No. 12. Pp. 128–131.
12. Kozlov G.V., Dolbin I.V. Influence of the Real Level of Carbon Nanotube Anisotropy on the Reinforcement Degree of Polymer Nanocomposites // Izvestiya VUZov. Physics. 2017. Vol. 60, No. 6. Pp. 72–76.
13. Jan R., May P., Bell A.P., Habib A., Khan U., Coleman J.N. Enhancing the mechanical properties of BN
14. nanosheet-polymer composites be uniaxial drawing // Nanoscale. 2014. V. 6, N 9. P. 4889–4895.
15. Kim H., Kobayashi S., AbdurRahim M.A., Zhang M.J., Khusainova A., Hillmyer M.A., Abdala A.A., Macosko C.W. Graphene/polyethylene nanocomposites: Effect of polyethylene functionalization and blending methods // Polymer. 2011. V. 52, N 7. P. 1837–1846.
16. Yousefi N., Lin X., Zheng Q., Shen X., Pothnis J.R., Jia J., Zussman E., Kim J.-K. Simultaneous in situ reduction, self-alignment and covalent bonding in grapheme oxide/epoxy composites // Carbon. 2013.
17. V. 58, N 2. P. 406–417.
18. Kulichin V.G., Semakov A.V., Karbushev V.V., Plate N.A., and Picken S.J. Chaos-Order Transition in Critical Shear Flow Regimes of Polymer Melts and Nanocomposites. High-Molecular-Weight Compounds A, 2009, Vol. 51, No. 11, pp. 2044-2053.
19. Rizvanova P.G., Magomedov G.M., Kozlov G.V., Dolbin I.V. Local and spatial structure of a nanofiller in a polymer matrix and its influence on the properties of nanocomposites // Physics and Chemistry of Material Processing. 2019, No. 3. Pp. 40–45.
Review
For citations:
Tochiev D.S., Sapaev Kh.Kh., Davydova V.V., Dolbin I.V. THE ROLE OF FILLER ANISOTROPY IN FORMATION OF POLYMER COMPOSITES PROPERTIES. Proceedings of the Kabardino-Balkarian State University. 2024;14(2):113-118. (In Russ.) https://doi.org/10.31143/2221-7789-2024-2-113-118. EDN: QHVMBE
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