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POLYMERIZATION OF VINYL MONOMERS WITH THE PARTICIPATION OF A QUATERNARY AMMONIUM COMPLEX

https://doi.org/10.31143/2221-7789-2024-4-45-51

EDN: XPXHDY

Abstract

The paper examines the polymerization processes of vinyl monomers in the presence of initiating systems amine – alkylating agent, with the formation of quaternary ammonium compounds. Studying the mechanisms of polymerization, a similarity was found between the polymerization of vinyl monomers in the presence of the initiating system tertiary amine – alkylating agent, and the polymerization of quaternary am- monium salts. The analogy lies in the identity of the active initiating centers formed and the mechanisms of chain growth and termination. In this case, the quaternary ammonium salt formed, which initiates the polymerization of vinyl monomers, is an active chain growth agent.

About the Authors

Yu. A. Malkanduev
Kabardino-Balkarian State University
Russian Federation


A. T. Dzhalilov
Tashkent Scientific Research Institute of Chemical Technology
Russian Federation


A. A. Kyarov
Kabardino-Balkarian State University
Russian Federation


L. G. Grineva
Kabardino-Balkarian State University
Russian Federation


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Review

For citations:


Malkanduev Yu.A., Dzhalilov A.T., Kyarov A.A., Grineva L.G. POLYMERIZATION OF VINYL MONOMERS WITH THE PARTICIPATION OF A QUATERNARY AMMONIUM COMPLEX. Proceedings of the Kabardino-Balkarian State University. 2024;14(4):45-51. (In Russ.) https://doi.org/10.31143/2221-7789-2024-4-45-51. EDN: XPXHDY

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