Preview

Proceedings of the Kabardino-Balkarian State University

Advanced search

MEASUREMENT OF DEPOLARIZATION CURRENTS OF MULTILAYER POLYMER FILMS OF POLYDIPHENYLENE PHTHALIDE

https://doi.org/10.31143/2221-7789-2023-1-41-44

EDN: WRSPRE

Abstract

The depolarization currents of multilayer polymer films of polydiphenylene phthalide were measured us- ing the method of thermally stimulated depolarization in the range from 170 to 373 K. Based on experimental data, the dependence of the temperature of the maximum position of the peak of the depolarization current, the charge released during heating of the sample and the activation energy of relaxation processes on the number of layers of the polymer film is shown. The value of the polarizing electric field strength was 8 х 106 V/m. The rate of temperature change was 5 K/min. Two regions were detected on the depolarization current spectra. The first region is interpreted in the dipole charge approximation. The second area is explained by the presence of a wide distribution of traps occupied by injected charges.

About the Authors

V. Kh Ilyasov
Ukhta state technical university
Russian Federation


D. D. Karamov
Birsk branch of Bashkir state university
Russian Federation


A. N. Lachinov
Birsk branch of Bashkir state university
Russian Federation


A. F. Ponomarev
Institute of physics of molecules and crystals Ufa scientific center
Russian Federation


A. V. Moshelev
Institute of physics of molecules and crystals Ufa scientific center
Russian Federation


N. P. Bogdanov
Ukhta state technical university
Russian Federation


References

1. Lee J., Kim J. Material properties influencing the charge decay of electret filters and their impact on filtration performance // Polymers. 2020 V. 12, N 3. P. 721.

2. Пономарев А.Ф., Мошелев А.В., Ильясов В.Х., Лачинов А.Н., Салазкин С.Н., Шапошникова В.В., Шарапов Д.С., Корнилов В.М. Новые возможности эффективного влияния на транспорт зарядов во фталидсодержащих полиариленэфиркетонах // Высокомолекулярные соединения. Серия С. 2009. Т. 51,

3. № 7. С. 1300–1305.

4. Пономарев А.Ф., Мошелев А.В., Ильясов В.Х., Лачинов А.Н., Корнилов В.М., Салазкин С.Н., Шапошникова В.В., Шарапов Д.С., Буракова А.О., Улитин Н.В. Исследование спектров тока термостимулированной деполяризации сополимеров полиариленэфиркетонов // Вестник Казанского технологи- ческого университета. 2014. Т. 17, № 4. С. 159–163.

5. Saxena P., Shukla P. Studies of the effect of temperature on charge accumulation in PVDF-PMMA double-layered thin films based on depolarization current measurements // Journal of Elastomers & Plastics. 2021. V. 53, N 7. P. 886–901.

6. Li Y., Cheng S., Wang S., Yuan C., Luo Z., Zhu Y., Hu J., He J., Li Q. Multilayered ferroelectric polymer composites with high energy density at elevated temperature // Composites Science and Technology. 2021. V. 202. P. 108–594.

7. Лежнев С.К., Юсупов А.Р., Галиев А.Ф., Корнилов В.М., Гадиев Р.М., Лачинов А.Н. Электролюминесценция полимерной пленки, содержащей границу раздела полимер/полимер // Письма в Журнал экспериментальной и теоретической физики. 2019. Т. 110, № 7. С. 437–442.

8. Gadiev R.M., Lachinov A.N., Kornilov V.M. Salikhov R.B., Rakhmeev R.G., Yusupov A.R. Anoma- lously high conductivity along the interface of two dielectric polymers // Jetp Lett. 2010. V. 90. P. 726–730.

9. Yusupov A.R., Gadiev R.M., Lachinov A.N., Kornilov V.M., Kalimullina L.R., Galiev A.F., Kian M., Salazkin S.N. Effect of polymer structure on the transport properties along the polymer/polymer interface // Synthetic Metals. 2021. V. 274. P. 116–733.

10. Saxena P., Shukla P., Gaur M.S. Dielectric behavior and structural characterization of polymeric double layer thin films // Journal of Applied Polymer Science. 2019. V. 136, N 27. P. 47–724.

11. Лущейкин Г.А. Полимерные электреты. М.: Химия, 1984. 184 с.

12. Гороховатский Ю.А., Бордовский Г.М. Термоактивационная токовая спектроскопия высокоомных полупроводников и диэлектриков. М.: Наука, 1991. 248 с.

13. Лачинов А.Н., Ильясов В.Х., Пономарев А.Ф. О механизмах термостимулированной деполяризации в полидифениленфталиде // Химическая физика. 2009. Т. 28, № 8. С. 78–83.

14. Ionov A.N., Lachinov A.N., Rivkin M.M., Tuchkevich V.M. Low-resistance state in polydiphenilenephthalide at low temperatures // Solid State Communs. 1992. V. 82, N 8. P. 609–611.


Review

For citations:


Ilyasov V.Kh., Karamov D.D., Lachinov A.N., Ponomarev A.F., Moshelev A.V., Bogdanov N.P. MEASUREMENT OF DEPOLARIZATION CURRENTS OF MULTILAYER POLYMER FILMS OF POLYDIPHENYLENE PHTHALIDE. Proceedings of the Kabardino-Balkarian State University. 2023;13(1):41-44. (In Russ.) https://doi.org/10.31143/2221-7789-2023-1-41-44. EDN: WRSPRE

Views: 27

JATS XML


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2221-7789 (Print)