LUMINESCENCE IN COMPLEXES OF EUROPE WITH LIGAND OFLOXACIN BASED
https://doi.org/10.31143/2221-7789-2025-4-60-64
EDN: XRMZQH
Abstract
This study presents the first comprehensive investigation of the luminescent properties of europium(III) complexes with ofloxacin (OF). Optimal conditions for the formation of stable luminescent complexes, including pH and reagent concentrations, were determined. It was established that in the presence of ofloxacin, intense sensitized luminescence of Eu³⁺ ions is observed, caused by efficient energy transfer from the ligand to the central ion. A system- atic study of the influence of f- and d-element ions on the luminescent characteristics of the system was conducted, enabling an assessment of its selectivity and stability against interfering influences. The results of the work are of fundamental importance for understanding the processes of complex formation and energetic interactions of lanthanides in microheterogeneous environments, as well as of practical prospects for the development of new luminescent probes and analytical methods based on sensitized fluorescence of europium.
About the Authors
S. A. ElcheparovaRussian Federation
Z. Yu. Isupova
Russian Federation
A. V. Veresnikova
Russian Federation
A. A. Tatrokova
Russian Federation
I. A. Teplyakova
Russian Federation
A. A. Isupova
Russian Federation
References
1. Meshkova S.B., Doga P.G. Increase in the sensitivity of the luminescent determination of lanthanides using their complex compounds // Journal of Analytical Chemistry. 2020. T. 75,
2. No. 3. P. 209–229.
3. Beltyukova S.V., Kravchenko T.B., Poluektov N.S., et al. The use of nalidixic acid in luminescent analysis // Report of the USSR Academy of Sciences. Ser. B. 1983. No. 12. Pp. 29–32.
4. Beltyukova S V., Poluektov N.S., Gritsay T.L., et al. Luminescent determination of terbium and disirozium in lanthanide and yttrium oxides // Zavodskaya Laboratoriya. 1984. No. 12. Pp. 25–26.
5. Beltyukova S.V., Egorova A.V., Teslyuk O.I. Sensitization of europium and terbium fluorescence by nalidixic acid and its derivatives // Journal of Analytical Chemistry. 2000. Vol. 55, No. 7. Pp. 760–763.
6. Zhang T.L., Zhao H.C., Jin L.P. Photochemical fluorescence enhancement of the terbium-lomef-loxacing complex and its application // Talanta. 1999. V. 47. P. 77.
7. You F., Zhao H.C. Sensitized fluorescence of terbium-enoxacing complexes // Anal. Commun. 1999.
8. V. 36. P. 231.
9. Okana J.A., Callejon M., Barragan F.J. Terbium-sensitized lumines-cence determination of levoflox-acin in tablets and human urine and serum // Analyst. 2000. V. 125. P. 1851–1852.
10. Elcheparova S.A., Isupova Z.Yu., Novikova G.Ya., Veresnikova A.V., Kozheleva K.R., Shetov R.A., Dyshekova K.I., Batyrova M.B. Viscosity of Neodymium Carboxylate Solution // Izvestiya of Kabardino-Balkarian State University. 2024. Vol. 14, No. 3. Pp. 110–114.
11. RF Patent No. 2837076. A luminescent method for determining europium with ciprolet / S.A. Elcheparova, Z.Yu. Isupova, G.O. Molokanov, A.N. Beslaneeva, O.Yu. Yurchenko, A.S. Bondareva, I.A. Tatrokova (Teplyakova), and A.A. Tatrokova. Published on March 25, 2025.
12. Lauer R.S., Poluektov N.S. Microvolume Chromatographic Method for Determining Individual Rare Earth Elements in Their Mixture // Zavodskaya Laboratoriya. 1959. Vol. 25, No. 4. Pp. 391–396.
13. Alakaeva L.A. Spectrophotometric Methods for Studying Complex Compounds: A Textbook. Nalchik: Kab.-Balk. University, 2003. 62 p.
Review
For citations:
Elcheparova S.A., Isupova Z.Yu., Veresnikova A.V., Tatrokova A.A., Teplyakova I.A., Isupova A.A. LUMINESCENCE IN COMPLEXES OF EUROPE WITH LIGAND OFLOXACIN BASED. Proceedings of the Kabardino-Balkarian State University. 2025;15(4):60-64. (In Russ.) https://doi.org/10.31143/2221-7789-2025-4-60-64. EDN: XRMZQH
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