Preview

Proceedings of the Kabardino-Balkarian State University

Advanced search

THE STRUCTURAL INTERPRETATION OF AGGREGATION DEGREE OF NANOFILLER FOR NANOCOMPOSITES POLYMER/GRAPHENE

https://doi.org/10.31143/2221-7789-2024-1-15-19

EDN: HLVNBQ

Abstract

The analytical structural analysis of aggregation degree of nanofiller in nanocomposites polymer/graphene. It has been shown that this parameter at fixed content of nanofiller is determined by structure of aggregates (tactoids) of graphene in polymer matrix only, characterized by its fractal dimension. The dependence of aggregation degree on dimension of nanofiller tactoids is stronger, than on its content. This circumstance allows to proposed a new variant of percolation relationship for determination of reinforcement degree of polymer nanocomposites, which was confirmed the postulate about dependence of properties of these nanomaterials on structure of nanofiller aggregates. The nanofiller structure itself is defined by formation conditions of nanocomposites, that allows to predict their properties.

About the Authors

Gus. M. Magomedov
Dagestan State Pedagogical University
Russian Federation


I. V. Dolbin
Kabardino-Balkarian State University
Russian Federation


Yu. V. Kudrov
Russian State University of Tourism and Service
Russian Federation


Ya. A. Kochetkova
Russian State University of Tourism and Service
Russian Federation


References

1. Thostenson E.T., Li C., Chou T.-W. Carbon nanotube/carbon fiber hybrid multiscale // Composites Sci. Techn. 2005. V. 65, N 3. P. 491–516.

2. Šupova M., Martynkova G.S., Barabaszova K. Effect of Nanofillers Dispersion in Polymer Matrices:

3. A Review // Sci. Adv. Mater. 2011. V. 3, N 1. P. 1–25.

4. Kim H., Kobayashi S., AbdurRahim M.A., Zhang M.J., Khusainova A., Hillmyer M.A., Abdala A.A., Macosko C.W. Graphene/polyethylene nanocomposites: effect of polyethylene functionalization and blending methods // Polymer. 2011. V. 52, N 5. P. 1837–1846.

5. Kim H., Abdala A.A., Macosko C.W. Graphene/polymer nanocomposites // Macromolecules. 2010.

6. V. 43, N 16. P. 6515–6530.

7. Mikitaev A.K., Kozlov G.V., Zaikov G.E. Polymer Nanocomposites: Diversity of Structural Forms and Applications. Moscow: Nauka, 2009. 278 p.

8. Kozlov G.V., Dolbin I.V. Features of the Filler Aggregation Process in Polymer-Carbon Nanotube Nanocomposites // Applied Mechanics and Technical Physics. 2020. Vol. 61, No. 2. Pp. 125–129.

9. Kozlov G.V., Yanovsky Yu.G., Karnet Yu.N. Structure and Properties of Dispersed Polymer Composites: Fractal Analysis. Moscow: Al'yansstransatom, 2008. 363 p.

10. Mikitaev A.K. and Kozlov G.V. Description of the Enhancement Degree of Polymer/Carbon Nanotube Nanocomposites Using Percolation Models // Physics of the Solid State. 2015. Vol. 57, No. 5. Pp. 961–964.

11. Schaefer D.W., Justice R.S. How nano are nanocomposites? // Macromolecules. 2007. V. 40, N 24.

12. P. 8501–8517.

13. Hentschel H.G.E., Deutch J.M. Flory-type approximation for the fractal dimension of cluster-cluster aggregates // Phys. Rev. A. 1984. V. 29, N 3. P. 1609–1611.

14. Brown D.W., Ball R.C. Computer simulation of chemically limited aggregation // J. Phys. A: Math. Gen. 1985. V. 18, N 9. P. L517-L521.

15. Schaefer D.W., Zhao J., Dowty H., Alexander M., Orler E.B. Carbon Nanofibre reinforcement of soft materials // Soft Matter. 2008. V. 4, N 10. P. 2071–2079.

16. Xu Y., Hong W., Bai H., Li C., Shi G. Strong and ductile poly(vinyl alcohol)/graphene oxide compo- site films with a layered structure // Carbon. 2009. V. 47, N 15. P. 3538–3543.


Review

For citations:


Magomedov G.M., Dolbin I.V., Kudrov Yu.V., Kochetkova Ya.A. THE STRUCTURAL INTERPRETATION OF AGGREGATION DEGREE OF NANOFILLER FOR NANOCOMPOSITES POLYMER/GRAPHENE. Proceedings of the Kabardino-Balkarian State University. 2024;14(1):15-19. (In Russ.) https://doi.org/10.31143/2221-7789-2024-1-15-19. EDN: HLVNBQ

Views: 55

JATS XML


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2221-7789 (Print)