ABSORPTION AND LOW-FREQUENCY PROPERTIES OF POLYIMIDES WITH DIFFERENT MOLECULAR RIGIDITY
https://doi.org/10.31143/2221-7789-2024-1-20-25
EDN: MTSANE
Abstract
This work focuses on the absorption characteristics of polyimides with different molecular rigidity in the temperature range of 25–175 °C. The temperature dependences of conductivity were obtained, the absorption coefficients, dielectric characteristics ɛ’(ω), ɛ’’(ω) in the range of 10-1–10-3 Hz were calculated. Experimental data suggest that charge accumulation in the films is caused by Maxwell-Wagner polarization. The dependency between the polyimide rigidity and electrical and dielectric characteristics was not found.
About the Authors
A. A. PavlovRussian Federation
M. E. Borisova
Russian Federation
A. M. Kamalov
Russian Federation
S. A. Kyzyurov
Russian Federation
A. L. Didenko
Russian Federation
References
1. Kamalov A., Smirnova N., Kolbe K. et al. Activation of R-BAPB polyimide with cold plasma dielec- tric barrier discharge for improvement of cell-material interaction // Journal of Applied Polymer Science. 2022.
2. V. 139, N 42. P. 1–9.
3. Nazarychev V.M. Full-atomic computer modeling of thermoplastic polyimides with variable structure of diamine fragments: Diss. PhD. Phys.-math. Sciences. SPb., 2015. 147 p.
4. Borisova M.E. Galyukov O.V., Tsatsynkin P.V. Physics of dielectric materials. Electro-transfer and charge accumulation in dielectrics. SPb.: SPbSPU, 2004. 106 p.
5. Borisova M.E., Koikov S.N. Physics of Dielectrics. L.: LSU, 1979. 240 p.
6. Poplavko Yu.M., Pereverzeva L.P., Raevsky I.P. Physics of Active Dielectrics. Rostov-on-Don: SFU, 2009. 480 p.
7. Pavlov A., Borisova M., Kamalov A. et al. The effect of hydroxyapatite on the electrical properties of a polylactide-based composite // Proceedings of 2020 IEEE EIConRus. 2020. P. 1042–1044.
8. Borisova M.E. Physics of Dielectrics. Physical Foundations of Active Dielectrics. St. Petersburg: SPbPU, 2014. 120 p.
9. Zhurkov S.N., Vetegren V.I., Novak I.I., Kashintseva K.N. Study of Mechanically Strained Bonds in Polymers by Infrared Spectroscopy // Doklady Akademii Nauk SSSR. ZhZ. 1976. Vol. 176. Pp. 623–626.
Review
For citations:
Pavlov A.A., Borisova M.E., Kamalov A.M., Kyzyurov S.A., Didenko A.L. ABSORPTION AND LOW-FREQUENCY PROPERTIES OF POLYIMIDES WITH DIFFERENT MOLECULAR RIGIDITY. Proceedings of the Kabardino-Balkarian State University. 2024;14(1):20-25. (In Russ.) https://doi.org/10.31143/2221-7789-2024-1-20-25. EDN: MTSANE
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